1. 双金属协同化学 2. 金属卡宾类催化剂的设计及应用
主持国家自然科学基金青年(1项)、面上(2项)等项目,参与国家自然科学原创探索计划项目(排名第二)、重大项目研究计划子课题(排名第三),入选福建省高校“杰出青年科研人才培育计划”等;获澳门沙金在线平台第九届青年教师教学技能大赛一等奖。
1. Zhuo, K.; Liu, Y.; Ruan, K.; Hua, Y.; Lin, Y.-M*. ; Xia, H. * Ring contraction of metallacyclobutadiene to metallacyclopropene driven by π- and σ-aromaticity relay. Nature Synthesis, 2023, 2, 67-75 (Highlighted by ChemistryViews, Synform, ScienceNet etc.)
2. Liu, H.-C.;# Ruan, K.;#, Ma, K.; Fei, J.; Lin, Y.-M*.; Xia, H.* Synthesis of metalla-dual-azulenes with fluoride ion recognition properties. Nat. Commun. 2023, 14, 5583. (Highlighted by ChemistryViews)
3. Li, Q.; Cheng, S.; Huang, T.; Yang, F.; Lin, Y.-M.*; Gong, L.* Visible light-triggered selective C(sp2)-H/C(sp3)-H coupling of benzenes with aliphatic hydrocarbons. Nat. Commun. 2023, 14, 6366. (Highlighted by ChemistryViews, Synfact)
4. Yang, F.; Huang, T.; Lin, Y.-M.*; Gong, L.*. Advancements in organocatalysis for radical-mediated asymmetric synthesis: a recent perspective Chem Catal. 2024, 4. 100812.
5. Huang, H.C.; Lin, Y.-M.*; Gong, L.* Recent Advances in Photochemical Asymmetric Three-Component Reactions.
Chem. Rec. 2023. 23, e202300275.
6. Cui, F.-H.; Li, Q.; Gao, L.-H.; Ruan, K.; Ma, K.; Chen, S.; Lu, Z.; Fei, J.; Lin, Y.-M.;* Xia, H.* Condensed Osmaquinolines with NIR-II Absorption Synthesized by Aryl C-H Annulation and Aromatization. Angew. Chem., Int. Ed. 2022, 134, e202211734.
7. Cui, F.-H.; Hua, Y.; Lin, Y.-M*.; Fei, J.; Gao, L.-H.; Zhao, X.; Xia, H. * Selective Difunctionalization of Unactivated Aliphatic Alkenes Enabled by a Metal−Metallaaromatic Catalytic System. J. Am. Chem. Soc. 2022, 144, 2301-2310 (入选ESI高被引).
8. Wang, H.; Ruan, Y.; Lin, Y.-M*.; Xia, H.* Direct amidation of metallaaromatics: access to N-functionalized osmapentalynes via a 1,5-bromoamidated intermediate. Chem. Sci., 2021, 12, 6315-6322(入选 2021 Chemical Science HOT Article Collection and Most popular 2021 main group, inorganic and organometallic chemistry articles).
9. Wang, H.; Lin, Y.-M*.; Chen, S.; Ruan, Y.; Xia, H.* Metallacycle Expansion and Annulation: Access to TetrazoloFused Osmacycles by Reaction of Cyclic Osmium Carbyne with Sodium Azide. Chin. J. Chem. 2021, 39, 3435-3442.
10. Wen, Z.-R; Guan, Z.-J.; Zhang, Y.; Lin, Y.-M*.; Wang, Q.-M, Au7Ag9(dppf)3(CF3CO2)7BF4]n: A Linear Nanocluster Polymer from Molecular Au7Ag8 Clusters Covalently Linking by Silver Atoms. Chem. Commun. 2019, 55, 12992-12995.
11. Guan, Z.-J.; Hu, F.; Yuan, S.-F.; Nan, Z.-A.; Lin, Y.-M*.; Wang, Q.-M*. The stability enhancement factor beyond eightelectron shell closure in thiacalix[4]areneprotected silver clusters. Chem. Sci., 2019,10, 3360-3365.
12. Li, J.; Lin, Y.-M*.; Zhang, H.; Chen, Y.; Lin, Z.; Xia, H.*, Access to Metal‐bridged Osmathiazine Derivatives by a Formal [4+2] Cyclization. Chem. Eur. J. 2019, 25, 5077-5085.
13. Guan, Z.-J.; Zeng, J.-L.; Yuan, S.-F.; Hu, F.; Lin, Y.-M*.; Wang, Q.-M*. Au57Ag53(C=CPh)40Br12: A Large Nanocluster with C1 Symmetry. Angew. Chem. Int. Ed. 2018, 57,5703-5707.
14. Du, Y.; Guan, Z.-J.; Wen, Z.-R.; Lin, Y.-M*.; Wang, Q.-M*. Ligand-Controlled Doping Effects in Alloy Nanoclusters Au4Ag23 and Au5Ag24. Chem. Eur. J., 2018, 24, 16029-16035.
15. Li, J.; Kang, H.; Zhuo, K.; Zhuo, Q.; Zhang, H.; Lin, Y.-M*. Xia, H.* Alternation of Metal-Bridged Metallacycle Skeletons: From Ruthenapentalyne to Ruthenapentalene and Ruthenaindene Derivative. Chin.J. Chem., 2018, 36, 1156-1160.
16. Zhou, X.; Li, Y.; Shao, Y.; Hua, Y.; Zhang, H.; Lin, Y.-M*. Xia, H.* Reactions of Cyclic Osmacarbyne with Coinage Metal Complexes. Organometallics, 2018, 37,1788-1794.
17. Guan, Z.-J.; Zeng, J.-L.; Nan, Z.-A.; Wan, X.-K.; Lin, Y.-M*.; Wang, Q.-M*. Thiacalix[4]arene: New protection for metal nanoclusters. Sci. Adv. 2016; 2 : e1600323.
18. Zeng, J.-L.; Guan, Z.-J.; Du,Y.; Nan, Z.-A.; Lin, Y.-M*.; Wang, Q.-M*. Chloride-Promoted Formation of a Bimetallic Nanocluster Au80Ag30 and the Total Structure Determination. J. Am. Chem. Soc. 2016, 138, 7848−7851.
19. Wang, J.-Y.; Liu, K.-G.; Guan, Z.-J.; Nan, Z.-A.; Lin, Y.-M*.; Wang, Q.-M*. [MnIIIMnIV2Mo14O56]17–: A Mixed-Valence Meso-Polyoxometalate Anion Encapsulated by a 64-Nuclearity Silver Cluster. Inorg. Chem., 2016, 55, 6833–6835.
20. Liu, K.-G.; Liu, X-Y.; Guan, Z.-J; Shi, K*; Lin, Y.-M*.; Wang, Q.-M. The transformation of polyoxometalate in the formation of intercluster compound [Ag41(α-SiW10O37)(tBuC=C)27(CH3CN)3][β-SiW12O40]. Chem. Commun. 2016, 52, 3801-3804.
21. Wang, Q.-M*.; Lin, Y.-M.; Liu, K.-G. Role of Anions Associated with the Formation and Properties of Silver Clusters.Acc. Chem. Res., 2015, 48, 1570–1579.
22. Liu, K.-G.; Chen, S.-K.; Lin, Y.-M*.; Wang, Q.-M*. An organic anion template: a 24-nucleus silver cluster encapsulating a squarate dimer. Chem. Commun., 2015,51, 9896-9898.
23. Lin, Y.-M*.; Guan, Z-J; Liu, K.-G.; Jiang Z.-G.; Wang, Q.-M*. Assembly of silver alkynyl compounds with various nuclearities. Dalton Trans., 2015,44, 2439-2446.
24. Jiang, Z.-G.; Shi, K.; Lin, Y.-M*.; Wang, Q.-M*. [Ag70(PW9O34)2(tBuC≡RC)44(H2O)2]8+: ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions. Chem. Commu., 2014, 50, 2353-2355.